Electronic Effects

IMPORTANT

Electronic Effects: Overview

This topic covers concepts, such as, Electron Displacement Effects in Covalent Bonds: Electronic Effects, Localised Electrons, Applications of Electromeric Effects & Application of Mesomeric Effect etc.

Important Questions on Electronic Effects

MEDIUM
IMPORTANT

Question Image

Question Image

Among these compounds,  the correct order of C–N bond length is :

EASY
IMPORTANT

Rank the following free radicals in order of decreasing stability:

I C 6 H 5 C HC 6 H 5

I I C 6 H 5 - C H - C H = C H 2

I I I C H 3 - C H - C H 3

I V C 6 H 5 - C H - C H 3

VCH3CH2CH2CH2CH2

Question Image

MEDIUM
IMPORTANT

In which of the following pairs, is the first species is more stable than second?

MEDIUM
IMPORTANT

In which of the following molecules π-electron density in ring is maximum ?

MEDIUM
IMPORTANT

In which of the following molecules π-electron density in ring is minimum ?

EASY
IMPORTANT

Which of the following compounds has maximum electron density in ring ?

EASY
IMPORTANT

Which of the following compounds has maximum electron density in ring ?

EASY
IMPORTANT

Question Image

In phenol, π - electron - density is maximum on

EASY
IMPORTANT

Question Image

Among these canonical structures of pyridine, the correct order of stability is

MEDIUM
IMPORTANT

The most stable resonating structure of following compound is

Question Image

EASY
IMPORTANT

For phenol, which of the following resonating structure is the most stable?

EASY
IMPORTANT

In which of the following molecules resonance takes place through out the entire system

MEDIUM
IMPORTANT

The increasing order of basic strengths in their aqueous solutions is:

 NH3,CH3NH2,(CH3)2NH,(CH3)3N

EASY
IMPORTANT

Hyperconjugation involves overlap of the following orbitals

MEDIUM
IMPORTANT

The reaction of ethene is the presence of H+ can be example for -E-effect.

MEDIUM
IMPORTANT

Which one of the following does not exhibit electromeric effect?

MEDIUM
IMPORTANT

Ethers do not exhibit electromeric effect but aldehydes and ketones exhibit electromeric effect, why?

MEDIUM
IMPORTANT

Give some examples of the electromeric effect.

MEDIUM
IMPORTANT

Due to which hyperconjugation the dipole moment of alpha-haloalkenes get augmented.

EASY
IMPORTANT

_____ hyperconjugation phenomenon is observed in α−halo alkenes.